Mechano-Optical Switching of a Single Molecule with Doublet Emission

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The ability to control the photon emission from single-molecule quantum emitters is the key toward their implementation in optoelectronics. Here we demonstrate that the emission wavelength of a single copper-phthalocyanine (CuPc) molecule can be reproducibly tuned by atomic-scale manipulations on the surface of an ionic crystal, using a scanning probe light microscope. We explain this by the effect of the local dielectric environment on the molecular emitter.

By precise centering above Na or Cl ions of a 2D NaCl crystal lattice, the photon emission wavelength of a single molecule of CuPc can be effectively tuned.
Description
By precise centering above Na or Cl ions of a 2D NaCl crystal lattice, the photon emission wavelength of a single molecule of CuPc can be effectively tuned.

Contact person: Mgr. Martin Švec, Ph.D.

Collaborating institutions:

Regional Centre of Advanced Technologies and Materials,

Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences,

Instituto de Ciencia de Materiales de Madrid, CSIC, Spain,

Instituto de Física Fundamental, CSIC, Madrid, Spain,

Department of Petrochemistry and Refining, University of Kinshasa, Kinshasa, Democratic Republic of Congo