Thin films of transition metal complexes with vacant positions in the ligand field for gas sensing application

Abstract
Chemical gas sensors are crucial to detect and analyze pollutant and hazardous gases that are not only harmful to humans and animals e.g. ozone and nitrogen oxides but also endangering life on earth in a wider sense. Current sensors are typically limited by selectivity, sensitivity, detection limit and response time, thus, a new generation of sensors is needed. We propose to develop chemical sensors where the active layers are based on new Ni(II) coordination complexes with a vacant site in their ligand sphere. We will use this novel approach to prepare thin film structures of these nanomaterials and test their sensing abilities towards the environmental hazardous gases: NOx, O3, CO2, NH3 and volatile organic compound vapors. The chemiresistive properties will be recorded and analyzed to gain information on sensitivity and detection limits, selectivity, response and recovery times. We will use the results to tailor the material, structure and composition to produce cheaper, reusable, durable, innovative sensors with low power consumption.