An international team of researchers headed by young Oxford physicist Sam Vinko created an unique state of matter by isochorically heating a thin aluminium foil using a tightly focused X-ray beam produced by the LCLS (Linac Coherent Light Source) free-electron laser in California. Solid-density plasmas at a temperature > 106 K were produced under these irradiation conditions. By using the LCLS pulse, the authors have been able to study extremely well-defined hot-dense plasma states for the first time, with unprecedented detail. Detailed simulations of the X-ray-matter interaction process conducted with a radiative-collisional code further showed good qualitative agreement with the experimental results, providing additional insight into the evolution of the charge state distribution of the system, the electron density and temperature, and the timescales of collisional processes. These results should feed back into future high-intensity X-ray experiments involving dense samples, such as X-ray diffractive imaging of biological systems, material science investigations, and the study of matter in extreme conditions.